System manufacturers, Dürr Systems GmbH and Caloric Anlagenbau GmbH, will collaborate in the field o... ...more
Once more Calorics’ advanced hydrogen technology supports a greenfield development polysilicon prod... ...more
The Calcor standard process is a reforming process combined with a CO2 recovery and a CO purification step. The feed is mixed with a split stream of hydrogen, then preheated prior to passing a catalytic hydrogenation and adsorptive sulphur removal. The feed is then mixed with CO2. Whilst passing the catalyst in the reformer tubes, the mixture of CO2 and feed is converted into a syngas consisting of carbon monoxide together with H2, CO2 and CH4. The heat for this endothermic reaction is generated by a high velocity burner firing into the reformer with circular arranged reformer tubes. The heat is transferred by radiation and convection. After leaving the reformertubes, the syngas is cooled to ambient temperature prior to undergoing the CO2 removal and recovery. In this process step the CO2 from the reformer flue gas as well as the CO2 from the raw gas is absorbed in packed towers at ambient temperature by caustic solution (MEA). In a stripper, the CO2 is separated from the scrubbing liquid and recycled via a preheater to the reforming process. The reboiler is heated by steam generated in the waste heat boiler fired by the hot flue gas from the reformer. The syngas which typically consists of 70 % by vol. CO and 30 % by vol. H2 and still carries traces of CO2 and CH4 enters the CO purification step. The tail gas separated in the CO purification step is either totally returned to the reformer as fuel, or H2 is extracted from and exported as technical grade hydrogen.
The selective properties of membranes make it possible to simultaneously separate H2 and CO2 from the CO product, which results in a simplified design of the Calcor process. In this "economy" version of the Calcor process, the CO2 recovery part of the process is deleted and imported CO2 is used instead of recovered CO2. This version is preferably used at locations, where low cost CO2 is available or CO2 can be imported economically. Since the major part of the production costs are capital costs, depreciation and interest rather than utility and energy costs, the economy process offers an additional advantage for the production of small quantities of CO.
|
Typical feed:
Capacity range: CO purity: CO supply pressure: Operation:
CO through CO2 Reforming |
|
For more information about CO Generation please contact us:
Phone: +49 (0)89-89 819-250 · email: CO@caloric.com · Contact form